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Fundamental understanding on the dynamic reactions of liquid gallium with aluminum

Li et al. | Sep 11, 2026

Fundamental understanding on the dynamic reactions of liquid gallium with aluminum
Image credit: David Hofmann

This study investigates the dynamic reaction between liquid gallium and aluminum, which poses a challenge when using high-performance gallium-rich thermal interface materials for electronic cooling. Through the usage of in-situ microscopy, we show that while aluminum oxide coatings slow gallium-induced damage, nanometer-thick iridium coatings effectively prevent reaction and surface degradation at device-operating temperatures. These findings highlight a promising thermal-cooling architecture for extending the lifespan and reliability of high-power electronic heat dissipation systems.

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Spectrophotometric comparison of 4-Nitrophenyl carbonates & carbamates as base-labile protecting groups

Kocalar et al. | Dec 12, 2022

Spectrophotometric comparison of 4-Nitrophenyl carbonates & carbamates as base-labile protecting groups

In organic synthesis, protecting groups are derivatives of reactive functionalities that play a key role in ensuring chemoselectivity of chemical transformations. To protect alcohols and amines, acid-labile tert-butyloxycarbonyl protecting groups are often employed but are avoided when the substrate is acid-sensitive. Thus, orthogonal base-labile protecting groups have been in demand to enable selective deprotection and to preserve the reactivity of acid-sensitive substrates. To meet this demand, we present 4-nitrophenyl carbonates and carbamates as orthogonal base-labile protecting group strategies.

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Electrocatalytic oxidation of furfural on Co3O4/nickel foam catalyst: performance and mechanistic study

Song et al. | Jul 19, 2026

Electrocatalytic oxidation of furfural on Co<sub>3</sub>O<sub>4</sub>/nickel foam catalyst: performance and mechanistic study
Image credit: Shraga kopstein

In this study, the authors hypothesized that the unique redox properties of cobalt oxide (Co3O4), combined with the conductive nature of the nickel foam (NF) substrate, synergistically enhances the catalytic performance for furfural oxidation. The study showed successful synthesis of Co3O4 nanoflowers directly grown on NF and tested their capacity to serve as a highly efficient electrocatalyst for furfural oxidation. Beyond furfural oxidation, this study also offers broader implications for sustainable chemistry by establishing design principles for efficient nucleophilic oxidation reaction catalysts, demonstrating an energy-saving alternative to conventional oxygen evolution reaction-coupled processes, and showcasing how biomass conversion can be integrated with renewable energy systems.

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